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Why do some people experience an electric shock when a metal spoon touches their filled tooth?
For a nerve-wracking experience involving the oxidation of elemental aluminum, bite a piece of aluminum foil with a tooth filled with dental amalgam (used for dental fillings). The aluminum behaves as an anode and releases electrons to the amalgam (a mix of silver, tin, and mercury). The amalgam behaves as a cathode by transferring these electrons to oxygen, which then combines with hydrogen ions to form water. The slight current that results produces a jolt of . . . ouch . . . pain.

Why are decorative items plated with silver or gold?

Silver and gold metals are expensive metals. Some people desire to have silverwares in their homes – utensils, spoons, forks, etc., or heavy gold jewelry, as a mark of being fashionable and having good taste. But these are expensive to have them in pure silver. So a cheap metal such as low-grade steel or iron is first made into a desired object, say a spoon. Then these items are coated with silver by electroplating. Same is true about gold plated jewelries. 
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