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Organohalogen compounds
We have come a long way since the primitive days of medicine when calling a doctor and undergoing surgery was a last resort, the alternative being certain death. Whilst even today few people relish a trip to hospital, surgery is no longer such a life–threatening or unduly painful experience because of organohalogen compounds.
The substitution of a chlorine atom into a molecule of the organic family known as the alkanes results in a compound with anaesthetic properties – trichloromethane (Chloroform) was a clear example. Increasing the number of chlorine atoms in the compound increases the depth of anaesthesia given, but unfortunately also increases the toxicity of the compound.
Carbon–fluorine bonds are very stable and so their presence in a compound leads to non–flammable, non–toxic and unreactive properties. Halothane, 2–bromo–2–chloro–1,1,1–trifluoroethane is an effective compound giving deep yet safe anaesthesia.  
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