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Carbon has four unpaired valence electrons. As shown in the below figure, each of these electrons is available for pairing with an electron from another atom, such as hydrogen, to form a covalent bond.
Methane
Four valence electrons of carbon, pairs with four hydrogen atoms to form methane.
The hydrocarbons in which each carbon atom is bonded to four neighboring atoms by four single covalent bonds are known as saturated hydrocarbons.  The term saturated means that each carbon has as many atoms bonded to it as possible. Eg: Methane, Ethane, Propane etc,.
A hydrocarbon containing a multiple bond–either double or triple–is known as an unsaturated hydrocarbon . Because of the multiple bond, two of the carbons are bonded to fewer than four other atoms. These carbons are thus said to be unsaturated . Eg: Ethene, Butene, Ethyne, Octyne etc,.
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